42799
博碩士論文
Burton, Graham William
trans-1,2-Dichloro-1,2-dihydronaphthalene has been obtained as the major product of the photochlorination of naphthalene at low temperature, and is the first authentically described naphthalene dichloride. Its further reaction with chlorine, under heterolytic conditions gives, in part, a new naphthalene tetrachloride, whose configuration has been assigned, by 1H n.m.r., as being that of the r-1,c-2,c-3,t-4-isomer. The assigned configuration and conformation of the compound are confirmed by its b...